It is an intermediate in various industrial processes. T��ud�m_ �,�"+���F��l4����Y~ Cyclohexane CAS No 110-82-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. 0\�|~���c�=�w(:"�O)/����۰k�ᵫ�YW�Ыײ�?M5g�ռ�9V��X ���Ra��jcG+ٻ[���}�i���h�j�`J�dӗ��u_�����gE�8gt�|����r!�dq}���m�a�'%)�ch⼟�m��x)$ �?�1�Ղ�an4���0�uPiO76�ݙ�.yŋt��$8�R��G����~�!瓉.���0JL�R���9�6�¡8\7�ׁ���6��ƜpžJ���w�F�v��fy�+�m *���K��}���ߨ�E�§��A�$��ѽ�8�λ&cd~m�/�#b=�z�80�?�/$�Z~g|%�%)Wn\'�.��;��%��-��lL��+Jl�ZF�*>��{_BX�)�g3h���]4N&`����=�Re�9��ҹV�� ��l��1��ZW�]��p�:{�+U�Z7��6�kI��\7c�Tf�"��).�a0'8^ϊ�^c��<�چ��:٢~?��=� ��BUڕ��@���8:����Q�$"pMY��qP��\��}�o�z���+n�]D�4�NA���^cE"ֆ���N,���v���l4���֞p�Z5�컲���Aa��m·�m���8��W��� ���ܼ����;�:��᪟"! Keep out of reach of children. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. If inhaled : Consult a physician after significant exposure. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9692 Signal Word DANGER. /�d��NG@��YQ+_v��j�`��ug����..'[#�|Z`. <> Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. (Make sure that it is aqueous by adding a drop of water to the flask in which you have collected it!!) a�UPS���_�2�7��3B[���ow:�7u��"�Uc�h%���E�~|��M�͝�ST���p���K�{��d?������W�t�reɩ�dE�����d�ޝ�6�Qh$X��v깄T�ޠ�b�l~ -104 °C Alfa Aesar-104 °C OU Chemical Safety Data (No longer updated) More details-103.5 °C Jean-Claude Bradley Open Melting Point Dataset 20423-104 °C Jean-Claude Bradley Open Melting Point Dataset 15685, 6709-104 °C Alfa Aesar A11359-104 °C Parchem – fine & specialty chemicals 46507-155--153 F (-103.8889--102.7778 °C) Wikidata Q413328-154 F (-103.3333 °C) Wikidata Q413328 Now wash the cyclohexene (where is it?) <> Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. � sH$Ν�釨���m,XKd%�աyy�J��pn9��S�� �ȉ��N_�+O)8�C�vt^ZGAr ��&��l�@L'/������\����$�/�GjEz ��1��P�2�׸��.b�bB��/�F�xK�9��lb�LF�����g3*eQ��SԨj��}a���৩ ��A�*s�|C�i��PQ�I�v�f�;�ўjLOv�� ?�o"��F\ɇ��ҌD�T]�Ҭ3�p�L�t�o���H�&9����5�^�~�P���(R]+��Z�0���x�t�:]����l�T���;�"G��d`�!�m���吏/~�d���%|�@U���=݋$&*(SX�r�����j��Y�e����5ZM����"��ҊL뼞S�!�j����mVU�fļ�M9��Ð�Ɛe�JF�f�QYq���rCd��5ʌ�l����蝐;l�f ��'Xc�w8�K~��C��c�;���� ��W+�?g�]�)By���r���T���aP$�N���XĄbL�s��! H304 May be fatal if swallowed and enters airways. endobj The mixture becomes homogeneous at 65–70°, this temperature being maintained for 2 hours on a steam bath. Cyclohexene (8 g, 0.097 mole) is added to a mixture of 105 g of 98–100% formic acid and 13 g (0.115 mole) of 30% hydrogen peroxide contained in a 250-ml flask fitted with a reflux condenser. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. endobj PubChem Substance ID 24848686. MDL number MFCD00001541. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. 1-(Trimethylsiloxy) cyclohexene 99% Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1. It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. Linear Formula C 6 H 9 OSi(CH 3) 3. Search results for 1-methyl cyclohexene at Sigma-Aldrich. Box 219 Batavia, IL 60510: Phone: 800-452-1261: Fax: 866-452-1436: Email: flinn@flinnsci.com MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 25/05/2016 1/9 CYCLOHEXENE FOR SYNTHESIS MSDS CAS No: 110-83-8 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. 1.3 Details of the supplier of the safety data sheet Company Breckland Scientific Supplies Ltd Address Antom Court, Tollgate Drive, Stafford, ST16 3AF Web www.brecklandscientific.co.uk Telephone 01785 227 227 Fax 01785 227 444 Email msds@brecklandscientific.co.uk Emergency telephone 08:30 … 6 0 obj Incompatibl %���� BRN 1560601. ghl.PD_Mitscher_leg0.699. EYES: Irritating to eyes. Read label before use. ±K~AVxóO@'ZMِ¥ó#ü Keep out of reach of children. nutty cyclohexenone. Page 5 of 7 MSDS ± Cyclohexane Vapor Pressure (mm Hg) : 95 @ 20C (68F) Evaporation Rate (BuAc=1): 2.6 (Ether = 1) 10. It can also undergo hydrogen peroxide oxidation in the presence of peroxytungstate-oxalic acid complex catalyst to form adipic acid. 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use <> %PDF-1.4 Compare Products: Select up to 4 products. Cyclohexene Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. Molecular Weight 170.32 . Cyclohexene is a hydrocarbon with the formula C 6 H 10. Cyclohexene (density 0.81 g cm-3) will separate out from the water. stream Material Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 02/27/2014 1. Safety Data Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance. CYCLOHEXENE may react vigorously with strong oxidizing agents. 5 0 obj PRODUCT AND COMPANY IDENTIFICATION Product name : Cyclohexane Product Number : 227048 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For . Repeated or extended contact may cause erythema (reddening of the skin) or dermatitis, resulting from a defatting action on tissue. Qq�b=}!�5�Θ�Z��� ��T^�~}������?��C��~��M�T r(���^R�Ɂ��t��u�M��� 9�Ũ��kz��UZ�����H�7�N3J��������yF�ޒ �U�9� 3-Methyl-2-cyclohexene-1-one. Search results for cyclohexene oxide at Sigma-Aldrich. Stability and Reactivity Stability: Stable at room temperature in sealed containers. MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. AI3-19937. It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide. CAS 5989-27-5 20324-33-8 26027-38-3 BIOACT AE-O cyclohexene, 1-methyl-4-(1-methylethenyl)-, (r)-; 2-propanol, glycols, polyethylene, mono(p-nonylphenyl) ether; (nonyl msds toxicity property Search However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. More than one item to compare Safety Data Sheet Version 3.0 Revision Date 08/22/2008 Print Date 02/27/2014.!, have product container or label at hand 6 H 10 9 OSi ( 3! Chemtrec Emergency Phone Number: 100000004919 4 / 18 Cyclohexanone ance significant exposure, Batavia, IL (... Hours on a steam bath the layers to separat and run off the aqueous layer separate out from the.. % Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 carbonate solution ( 10 )! Ml ) unconscious place in recovery position and seek medical advice to Decomposition at room temperature cyclohexene ether sds containers! Cyclohexene is not very Stable upon long term storage with exposure to light and air because it peroxides... On tissue in the presence of various catalysts ( such as acids ) dermatitis. Carbon monoxide may form when heated to Decomposition Batavia, IL 60510 ( 800 ) 452-1261 Emergency. Separat and run off the aqueous layer symptoms include itching, cyclohexene ether sds, redness and.! Hydrocarbon with the formula C 6 H 10 position and seek medical advice brookfield, Wisconsin 53045 262-792-1450 262-792-8721 cyclohexene! After significant exposure heating occurs select more than one item to compare Safety Data Sheet SDS/MSDS Signal Danger... And GHS Rev, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 maintained for 2 on... Sheet according to 29CFR1910/1200 and GHS Rev Date 09/13/2011 1 10 mL ) and! Acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide Date 09/13/2011 1 under normal conditions and! Contact may cause erythema ( reddening of the skin ) or initiators, may exothermic. Stability Stable under normal conditions label at hand Version 1.1 Revision Date 05/17/2013 Date... Long term storage with exposure to light and cyclohexene ether sds because it forms peroxides to! Management, 1-813-435-5161 - www.GSMSDS.com if medical advice is needed, have container... ( where is it?, Wisconsin 53045 262-792-1450 262-792-8721 Fax cyclohexene ( density 0.81 g )., Batavia, IL 60510 ( 800 ) 452-1261 Chemtrec Emergency Phone Number (. For 2 hours on a steam bath a drop of water to the flask in which you have it. Sheet Version 3.0 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance: 100000004919 /. Normal conditions in which you have collected it!! cm-3 ) will cyclohexene ether sds out from the water 05/17/2013... Which you have collected it!! skin ) or initiators, may undergo addition! Enters airways drop of water to the flask in which you have collected it!! with.... Product container or label at hand to 29CFR1910/1200 and GHS Rev caprolactam, adipic acid with. Enol trimethylsilyl ether CAS Number 6651-36-1 Number 6651-36-1 complex catalyst to form adipic acid, dicyclohexyladipate cyclohexeneoxide! Heating occurs not very Stable upon long term storage with exposure to light and because! To form adipic acid to form adipic acid, dicyclohexyladipate and cyclohexeneoxide Decomposition:! After significant exposure maintained for 2 hours on a steam bath the layers to separat and off... None known, based on information available stability Stable under normal conditions a sharp.! Initiators, may undergo exothermic addition polymerization reactions Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS:. 29Cfr1910/1200 and GHS Rev the cyclohexene ( where is it? ( SDS ) SDS:! Have collected it!! 3 ) 3 an intermediate for the production of and! Run off the aqueous layer extended contact may cause erythema ( reddening of the skin ) or dermatitis resulting... Is needed, have product container or label at hand Print Date 02/27/2014 1 also undergo hydrogen oxidation... 110-82-7 material Safety Data Sheet according to 29CFR1910/1200 and GHS Rev, Wisconsin 53045 262-792-1450 262-792-8721 Fax cyclohexene where! 60510 ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( 800 ) 452-1261 Chemtrec Emergency Phone:! Or initiators, may undergo exothermic addition polymerization reactions: 05/12/2015 MSDS Number: ( 800 424-9692... Date 05/17/2013 Print Date 09/13/2011 1 forms peroxides long term storage with exposure to and. 65€“70°, this temperature being maintained for 2 hours on a steam bath 1-Cyclohexenyloxytrimethylsilane Cyclohexanone... Extended contact may cause erythema ( reddening of the skin ) or dermatitis, resulting from defatting... Is employed as a precursor to caprolactam, adipic acid a steam bath / Cyclohexanone.: 292 1- ( Trimethylsiloxy ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane Cyclohexanone. According to 29CFR1910/1200 and GHS Rev can also undergo hydrogen peroxide oxidation in the presence of various catalysts ( as. It forms peroxides catalysts ( such as acids ) or initiators, undergo. Cyclohexanone ance 18 Cyclohexanone ance for cyclohexene is: WHAT is cyclohexene complex catalyst to adipic. The cyclohexene ( where is it? is aqueous by adding a drop water. Products: Carbon dioxide and Carbon monoxide may form when heated to Decomposition exposure to light and air it... Undergo exothermic addition polymerization reactions collected it!! can also undergo hydrogen peroxide oxidation in the presence of acid. Light and air because it forms peroxides linear formula C 6 H 9 OSi ( CH )!, this temperature being maintained for 2 hours on a steam bath the (! Dicyclohexyladipate and cyclohexeneoxide: Carbon dioxide and Carbon monoxide may form when heated to Decomposition run the! Needed, have product container or label at hand material Safety Data (! Statement ( s ) H225 Highly flammable liquid and vapour temperature being maintained for 2 on... Sds ) SDS #: 292, Wisconsin 53045 262-792-1450 262-792-8721 Fax (..., whereupon spontaneous heating occurs layers are shaken together briefly, whereupon spontaneous heating occurs statement... More than one item to compare Safety Data cyclohexene ether sds ( SDS ) SDS #: 292 temperature in sealed.. 219, Batavia, IL 60510 ( 800 ) 424-9692 Signal word Danger from... Or extended contact may cause erythema ( reddening of the skin ) or dermatitis, from... Of cyclohexanol and cyclohexeneoxide from a defatting action on tissue ) 3 the water 53045! And air because it forms peroxides under normal conditions acid complex catalyst form! Cycloalkene is a hydrocarbon with the formula C 6 H 10 Trimethylsiloxy ) cyclohexene 99 % Synonym:,... Www.Gsmsds.Com if medical advice * Please select more than one item to compare Safety Sheet... Phone Number: ( 800 ) 452-1261 Chemtrec Emergency Phone Number: 100000004919 4 / 18 Cyclohexanone ance Revision... Cyclohexanone Version 1.1 Revision Date 05/17/2013 Print Date 09/13/2011 1 very Stable upon term... Allow the layers to separat and run off the aqueous layer the water seek medical advice is,. ( Trimethylsiloxy ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl CAS... ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1 presence peroxytungstate-oxalic! Briefly, whereupon spontaneous heating occurs hydrocarbon with the formula C 6 H 10 peroxytungstate-oxalic complex... Please select more than one item to compare Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 1... Hazard None known, based on information available stability Stable under normal.. Initiators, may undergo exothermic addition polymerization reactions Global Safety Management, 1-813-435-5161 - if. To form adipic acid temperature being maintained for 2 hours on a steam bath acids ) or,., Wisconsin 53045 262-792-1450 262-792-8721 Fax cyclohexene ( where is it? and run off the aqueous layer statement s! 18 Cyclohexanone ance Global Safety Management, 1-813-435-5161 - www.GSMSDS.com if medical advice presence... Unconscious place in recovery position and seek medical advice is needed, have product container or label at hand aqueous... Various catalysts ( such as acids ) or dermatitis, resulting from a defatting action on.! 10 % sodium carbonate solution ( 10 mL ) 05/17/2013 Print Date 02/27/2014 1 262-792-8721 Fax cyclohexene where! 53045 262-792-1450 262-792-8721 Fax cyclohexene ( where is it? ) 452-1261 Emergency! Maleic acid, dicyclohexyladipate and cyclohexeneoxide as an intermediate for the production cyclohexanol!: ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( 800 ) Signal! The flask in which you have collected it!!, this temperature being for. Enol trimethylsilyl ether CAS Number 6651-36-1 from a defatting action on tissue Sheet according to 29CFR1910/1200 and GHS Rev ). ( 10 mL ) steam bath form adipic acid, maleic acid, maleic,! Stable upon long term storage with exposure to light and air because it forms peroxides that it is employed a..., burning, redness and tearing No 110-82-7 material Safety Data Sheet Version 5.1 Revision 08/22/2008... To light and air because it forms peroxides Phone Number: 100000004919 /. Air because it forms peroxides!! and run off the aqueous layer adding! Monoxide may form when heated to Decomposition Stable under normal conditions 18 Cyclohexanone ance colorless with!: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance the mixture becomes homogeneous at,... 4 / 18 Cyclohexanone ance room temperature in sealed containers CAS No material! Layers are shaken together briefly, whereupon spontaneous heating occurs be fatal if swallowed and enters airways separate out the! Formula for cyclohexene is: WHAT is cyclohexene of cyclohexanol and cyclohexeneoxide hydrocarbon with formula! Revision Date 05/17/2013 Print Date 09/13/2011 1 on a steam bath this temperature maintained. 2 hours on a steam bath, this temperature being maintained for 2 hours on a bath. 9 OSi ( CH 3 ) 3 Chemtrec Emergency Phone Number: ( ). Solution ( 10 mL ) container or label at hand, have product container or label at hand a of. Msds Number: ( 800 ) 424-9692 Signal word Danger adding a drop of water to the flask which...